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Byju's Answer
Standard XII
Chemistry
Gibb's Free Energy
The electrode...
Question
The electrode potential for the Daniell cell given is
1.1
V.
Z
n
(
s
)
|
Z
n
2
+
(
a
q
)
|
|
C
u
2
+
(
a
q
)
|
C
u
(
s
)
Write overall cell reaction and calculate the standard Gibb's energy for the reaction. [F
=
96487
c/mol].
Open in App
Solution
Z
n
+
C
u
2
+
→
Z
n
2
+
+
C
u
Δ
G
o
=
−
n
F
E
o
c
e
l
l
=
−
2
×
96487
×
1.1
=
−
212271.4
Joules.
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Similar questions
Q.
The standard electrode potential of a Daniell cell is
1.1
V
. Find the standard Gibbs energy for the reaction.
Z
n
(
s
)
+
C
u
2
+
(
a
q
.
)
→
Z
n
2
+
(
a
q
.
)
+
C
u
(
s
)
Q.
Calculate the equilibrium constant and free energy change of given following reaction for Daniell cell at 298 K temperature.
Z
n
(
s
)
+
C
u
2
+
(
a
q
)
⇌
Z
n
2
+
(
a
q
)
+
C
u
(
s
)
Cell potential
=
1.1
v
o
l
t
(
F
=
96500
coulomb)
Q.
The standard electrode potential
(
E
∘
)
for Daniel cell is + 1. 1 V. Calculate the
Δ
G
∘
for the reaction
Z
n
(
s
)
+
C
u
2
+
(
a
q
)
⟶
Z
n
2
+
(
a
q
)
+
C
u
(
s
)
(
1
F
=
96500
C
m
o
l
−
1
)
.
Q.
The standard electrode potential
(
E
∘
)
for Daniel cell is
+
1.1
V
. Calculate
Δ
G
∘
for the reaction.
Z
n
(
s
)
+
C
u
2
+
(
a
q
)
→
Z
n
2
+
(
a
q
)
+
C
u
(
s
)
(
1
F
=
96500
C
/
m
o
l
)
Q.
The cell reaction in Daniel cell is
Z
n
(
s
)
+
C
u
2
+
(
a
q
)
→
Z
n
2
+
(
a
q
)
+
C
u
(
s
)
and Nernst equation for single electrode potential for general electrode reaction
M
n
+
(
a
q
)
+
n
e
−
→
M
(
s
)
is
E
M
n
+
/
M
=
E
o
M
n
+
/
M
−
2.303
R
T
n
F
l
o
g
[
M
]
[
M
n
+
]
Derive Nernst equation for Daniel Cell.
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