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Question

The electrolytic reduction of nitrobenzene in strongly acidic medium produces:

A
Aniline
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B
p-Aminophenol
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C
Azoxybenzene
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D
Azobenzene
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Solution

The correct option is B p-Aminophenol
Electrolytic reduction of nitrobenzene in weakly acidic medium gives aniline but in strongly acidic medium. It gives para-amino phenol through the acid catalysed rearrangement of initially formed phenyl hydroxyl amine.


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