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Question

The equation of state of a gas is given by (P+aV3)(V−b2) = cT, where P, V, Tare pressure, volume and temperature respectively, and a, b, c are constants. The dimensions of a and b are respectively:

A
[ML8T2] and [L3/2]
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B
[ML5T2] and [L3]
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C
[ML5T2] and [L6]
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D
[ML6T2] and [L3/2]
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Solution

The correct option is B [ML8T2] and [L3/2]
Given, [P+aV3](Vb2)=cT
Dimension of aV3 = Dimensions of P
Dimensions of a = dimensions of PV3
[a]=[FAV3] (P=FA)
=[MLT2]L2×[L3]3=[ML8T2]
Dimensions of b2 = dimensions of V
[b]=[V]1/2=[L3]1/2 or [b]=[L3/2]

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