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Question

The equivalent weight of an element is 4. Its chloride has a vapour density 59.25. Then find the valency of element.

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Solution

molecular mass = 2 × Vapour density Molecular mass = 2 × 59.25 = 118.5The formula of the metal chloride = MClnMCln = 118.5M + n × Cl = 118.54 + n × Cl = 118.5n × Cl = 118.5 - 4 = 114.5n × 35.5 = 114.5n = 114.535.5 = 3.23 3Thus the valency of the element = 3

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