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Question

The equivalent weight of Cu2S (mol.wt.=M) in the following reaction is:
Cu2S+4MnO4Cu2+SO2+Mn2+

A
M/2
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B
M/6
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C
M/8
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D
M/4
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Solution

The correct option is B M/6
In this reaction copper +1 to copper +2
And sulphur 2 to sulphur +4
Total number of ions exchange in this reaction=(2-1)+(4-(-1))=6
Equivalent weight= Molecular weight/n factor
n factor is equal to number of ions change in a reaction.
So
equivalent weight=M/6

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