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Question

The equivalent weight of Na2S2O3(Mol. wt . = M ) in the reaction,


2Na2S2O3+I2Na2S4O6+2NaI is :

A
M/4
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B
M/3
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C
M/2
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D
M
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Solution

The correct option is D M
+22Na2S2O3+I25/2Na2S4O6+2NaI2+2x6=02+4x12=02x4=04x10=02x=44x=10x=+2x=104=52

Change in O.S.=5221=542=12

nfactor of Na2S2O3=12×2=1

Equivalentweight=Mol.wt.nfactor=M1

Hence, option D is correct.

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