The following table shows the tests a student performed on four different aqueous solutions which are X, Y, Z and W. Based on the observations provided, identify the cation present:
Chemical Test | Observations | Conclusions |
To solution X, ammonium hydroxide is added in minimum quantity first and then in excess. | A dirty white precipitate is formed which dissolves in excess to form a clear solution. | (i) |
To solution Y, ammonium hydroxide is added in minimum quantity first and then in excess. | A pale blue precipitate is formed which dissolves in excess to form a clear inky blue solution. | (ii) |
To solution W, a small quantity of sodium hydroxide solution is added and then in excess. | A white precipitate is formed which remains insoluble. | (iii) |
To a salt Z, calcium hydroxide solution is added and then heated. | A pungent smelling gas turning moist red litmus paper blue is obtained. | (iv) |
(i) Here solution X, must be zinc as, when ammonium hydroxide is added with zinc sulfate then, a dirty white precipitate of zinc (II) hydroxide is formed which form a clear solution in excess ammonium hydroxide. So, the cation present is Zn2+.
(ii) Here solution Y, must be copper as, when ammonium hydroxide is added with copper sulfate salt then, a pale blue precipitate of copper (II) hydroxide is formed which dissolves to form a clear inky blue solution in excess ammonium hydroxide. So, the cation present is Cu2+.
(iii) Here solution W, must be magnesium as, when sodium hydroxide is added with magnesium sulfate salt then, a white precipitate of magnesium hydroxide is formed which remains insoluble even after adding excess sodium hydroxide. So, the cation present is Mg2+.
(iv) Here salt Z, must be ammonium salt as when ammonium salt is added to calcium hydroxide and heated then a displacement reaction takes place in which calcium replaces ammonia to form calcium salt and ammonium hydroxide is formed which is a pungent-smelling gas that turns moist red litmus paper to blue due to its basic nature. So, the cation present in salt Z, is (NH4)+.