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Question

The following table shows the tests a student performed on four different aqueous solutions which are X, Y, Z and W. Based on the observations provided, identify the cation present:

Chemical Test

Observations

Conclusions

To solution X, ammonium hydroxide is added in minimum quantity first and then in excess.A dirty white precipitate is formed which dissolves in excess to form a clear solution.(i)
To solution Y, ammonium hydroxide is added in minimum quantity first and then in excess.A pale blue precipitate is formed which dissolves in excess to form a clear inky blue solution.(ii)
To solution W, a small quantity of sodium hydroxide solution is added and then in excess.A white precipitate is formed which remains insoluble.(iii)
To a salt Z, calcium hydroxide solution is added and then heated.A pungent smelling gas turning moist red litmus paper blue is obtained.(iv)

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Solution

(i) Here solution X, must be zinc as, when ammonium hydroxide is added with zinc sulfate then, a dirty white precipitate of zinc (II) hydroxide is formed which form a clear solution in excess ammonium hydroxide. So, the cation present is Zn2+.

(ii) Here solution Y, must be copper as, when ammonium hydroxide is added with copper sulfate salt then, a pale blue precipitate of copper (II) hydroxide is formed which dissolves to form a clear inky blue solution in excess ammonium hydroxide. So, the cation present is Cu2+.

(iii) Here solution W, must be magnesium as, when sodium hydroxide is added with magnesium sulfate salt then, a white precipitate of magnesium hydroxide is formed which remains insoluble even after adding excess sodium hydroxide. So, the cation present is Mg2+.

(iv) Here salt Z, must be ammonium salt as when ammonium salt is added to calcium hydroxide and heated then a displacement reaction takes place in which calcium replaces ammonia to form calcium salt and ammonium hydroxide is formed which is a pungent-smelling gas that turns moist red litmus paper to blue due to its basic nature. So, the cation present in salt Z, is (NH4)+.


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