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Question

The function of ZnCl2 in Lucas test for alcohols is:

A
to act as an acid catalyst and react with HCl to form H2ZnCl4
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B
to act as a base catalyst and react with NaOH to form Na2Zn(OH)4
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C
to act as an amphoteric catalyst
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D
to act as a neutral catalyst
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Solution

The correct option is A to act as an acid catalyst and react with HCl to form H2ZnCl4
The lucas reagent which is the mixture of HCl and ZnCl2 act as an catalyst for the reaction in which ZnCl2 act as an acid catalyst which react with HCl to form H2ZnCl4. The reagent is used to differentiate and categorize primary, secondary and tertiary alcohols.

2HCl+ZnCl2H2ZnCl4

Hence A is correct

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