The correct options are
A For the gas A,
a=0 and its dependence on P is linear at all pressure
B For the gas B,
b=0 and its dependence on P is linear at all pressure
D At high pressure, the slope is positive for all real gases
According to a real gas equation,
The constants 'a' and 'b': Van der Waals constant for attraction 'a' and volume 'b' are characteristic constants for a given gas.
(i)The 'a' values for a given gas are a measure of intermolecular forces of attraction. More are the intermolecular forces of attraction, more will be the value of a.
(ii)For a given gas van der Waals constant of attraction 'a' is always greater than van der Waals constant of volume 'b'.
(iii)The gas having a higher value of 'a' can be liquefied easily and therefore
H2 and He is not liquefied easily.
According to this, for gas A (Z>1), a=0 and its dependence on P is linear at all pressure and for gas B (Z<1), b=0
and its dependence on P are linear at all pressure.
Also,
At high pressure, the slope is positive for all real gases.
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