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Electrolytes

The heat of n...

Question

The heat of neutralisation is highest in the reaction between:

H N O_{3}

and

N H_{4} O H

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H C l

and

N a O H

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N H_{4} O H

and

C H_{3} C O O H

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N a O H

and

C H_{3} C O O H

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Solution

The correct option is C $H C l$ and $N a O H$
The heat of the neutralization of acid and base is maximum in the case of neutralization of strong acid and strong base.

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(e) HCl, H₂SO₄, HNO₃, CH₃COOH

H C l

N a O H

N H_{4} O H

N H_{4} O H

C H_{3} C O O H

Δ H^{\circ}

C H_{3} C O O H

\begin{matrix} Column - I & Column - II (Enthalpy change in kcal) & (Neutralisation) (A) & < 13.7 kcal & (p) & H C l (1 m o l) + N a O H (1 m o l) (B) & = 13.7 kcal & (q) & H F (1 m o l) + N a O H (1 m o l) (C) & > 13.7 kcal & (r) & N H_{4} O H (1 m o l) + H C l (1 m o l) (D) & = 27.4 kcal & (s) & N a O H (2 m o l) + H_{2} S O_{4} (1 m o l) (t) & N a O H (1 m o l) + C H_{3} C O O H (1 m o l) \end{matrix}

N H_{4} O H

C H_{3} C O O H

m o l^{- 1}

C H_{3} C O O H

m o l^{- 1}

N H_{4} O H

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