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Question

The hydrocarbon shown below is allowed to react(separately)with two sets of reducing agents.What are the respective products of these reactions?

230958_dc927e38d0634bea9c3f947aed1fced9.png

A
Na/liq.NH3H2/Pd/CHeptaneHeptane
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B
TranstransheptadieneCistransheptadiene
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C
TranscisheptadieneCisheptene
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D
Transtransheptadieneheptane
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Solution

The correct option is D TranstransheptadieneCistransheptadiene
Both catalysts are used for hydrogenation of alkynes to an alkene.

Alkyne reduction forms a trans product in the presence of Na in liq. ammonia and cis product in the presence of H2 in Pd
Option B is correct.

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