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Question

trans-2-Butene is allowed to react with D2 in the presence of nickel as catalyst. The product formed is:

A
(±) 2,3-dideuteriobutane
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B
meso-2,3-dideuteriobutane
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C
1,4-dideuteriotrans-2-buten
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D
2,3-dideuteriobutane
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Solution

The correct option is A (±) 2,3-dideuteriobutane
Trans-2-Butene is allowed to react with D2 in the presence of nickel as catalyst. The product formed is (±) 2,3 dideuteriobutane. The product is obtained due to syn addition of a molecule of deuterium across C=C double bond.

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