The increasing order of stability of the following free radicals is . 1.(CH3)2˙CH<(CH3)3˙C<(C6H5)2˙CH<(C6H5)3˙C2.(C6H5)3˙C<(C6H5)2˙CH<(CH3)3˙C<(CH3)2˙CH3.(C6H5)2˙CH<(C6H5)3˙C<(CH3)3˙C<(CH3)2˙CH4.(CH3)2˙CH<(CH3)3˙C<(C6H5)3˙C<(C6H5)2˙CH
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Solution
Radical is stabilized by α hydrogen. More the α-hydrogen more will be hyperconjugation more will be radical stabilization resonance.
Resonance is also a good stabilizing factor and is given preference than hyperconjugation.