The initial pressure, volume and temperature of an ideal gas are 1atm,200L and 300K respectively. The volume and pressure of the ideal gas are adiabatically changed to 74.3L and 4atm respectively. Then: [Take R=0.082L atm K−1mol−1]
A
Gas is monoatomic
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B
Gas is diatomic
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C
Final temperature is 446 K
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D
Gas has 8.13 moles
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Solution
The correct options are B Gas is diatomic C Final temperature is 446 K D Gas has 8.13 moles Given that Initial volume (Vi)=200 L Final volume (Vf)=74.3 L Initial pressure (Pi)=1atm Final pressure (Pf)=4atm Initial temperature (Ti)=300K For adiabatic process. PiVγi=PfVγf ⇒Pf=Pi(ViVf)γ ⇒4atm=(1 atm)(200L74.3 L)γ ⇒γ=ln(PfPi)ln(ViVf)=ln(41)ln(20074.3) ⇒γ≈1.4=75 (gas is diatomic) Now, PV=nRT PfVfPiVi=nRTfnRTi ⇒Tf=PfVfPiVi×Ti ⇒Tf=4×74.31×200×300 Tf=445.8≅446K and n=PiViRTi=1×2000.082×300(R=0.082L atm K−1mol−1) n=8.13 moles Hence, options (b),(c) and (d) are correct.