The correct option is B 120.6
The ionization potential of an element is 5.23 eV. This can also be expressed as 120.6 kcal/mole.
1ev=3.83×10−23 kcal
Hence, 5.23eV=5.23eV×3.83×10−23kcal1eV=20×10−23kcal
This is true for 1 atom. For 1 mole, the ionisation energy will be 20×10−23×6.023×1023=120.6 kcal/mol.