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Electrolytic Cell

The Kohlrausc...

Question

The Kohlrausch law is realted to:

A

Conductance of ions at infinite dilution

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B

Independent migration of ions

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C

Both (a) and (b)

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D

neither (a) and (b)

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Solution

The correct option is C Both (a) and (b)
Kohlrausch's law is applicable at the infinite dilution of the electrolyte at which the ions migrate independent of each other.
Hence, option C is correct.

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Q. State Kohlrausch Law, and write mathematical expression of molar conductivity of the given solution at infinite dilution.

Q. Assertion: If

λ_{N a^{+}}^{\circ} + λ_{C l^{-}}^{\circ}

are molar limiting conductivity of the sodium and chloride ions respectively, then the limiting molar conducting for sodium chloride is given by the equation:

λ_{N a C l}^{\circ} = λ_{N a^{+}}^{\circ} + λ_{C l^{-}}^{\circ}

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