The least basic among the given amines is

(C H_{3})_{3} N

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C_{2} H_{5} N H_{2}

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(C H_{3})_{2} N

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C_{6} H_{5} N H_{2}

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Solution

The correct option is D $C_{6} H_{5} N H_{2}$

Aromatic amines are less basic than aliphatic mines because on aromatic amines, lone pair of $N$ is involved with the ring and not so available for donation as compared to aliphatic amines.

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[AIIMS 1991; RPMT 2002]

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