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Question

The major product formed by the addition of 1 mole of HCl to 1,3-Butadiene at a low temperature (0oC or below) is:

A
3-chloro-1-butene
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B
1-chloro-2-butene
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C
2-chloro-2-butene
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D
chlorocyclobutane
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Solution

The correct option is B 3-chloro-1-butene
1,3-butadiene reacts with 1 mole of HCl at low temperature (00C or below) to form 3-chloro-1-butene.
This reaction is kinetically controlled reaction and 1,2-addition of HCl takes place.

CH2=CHCH=CH2+HCl00C or below−−−−−−CH2ClCH2CH=CH2

So answer is A.

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