The mixture that forms a maximum boiling azeotrope is:

Water + Nitric acid

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Ethanol + Water

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Acetone + Carbon disulphide

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Heptane + Octane

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Solution

The correct option is A Water + Nitric acid
Solutions that show a negative deviation from Raoult's law form maximum boiling azeotropes. Water and Nitric acid $\to$ forms a maximum boiling azeotrope.

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Question 25
On the basis of information given below mark the correct option. Information On adding acetone to methanol some of the hydrogen bonds between methanol molecules break.
(a) At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will show positive deviation from Raoult's law
(b) At specific composition methanol-acetone mixture will form maximum boiling azeotrope and will show positive deviation from Raoult's law
(c) At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will show negative deviation from Raoult's law
(d) At specific composition methanol-acetone mixture will form maximum boiling azeotrope and will show negative deviation from Raoult's law

Q. If two volatile liquids A and B form a maximum boiling azeotrope at

X_{A} = 0.3

.
For,

P_{A}^{\circ} = 200 t o r r and P_{B}^{\circ} = 400 t o r r

,the vapour pressure of the azeotropic mixture can exhibit a value of :

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The mixture that forms a maximum boiling azeotrope is:

The correct option is A Water + Nitric acidSolutions that show a negative deviation from Raoult's law form maximum boiling azeotropes. Water and Nitric acid → forms a maximum boiling azeotrope.

The correct option is A Water + Nitric acid
Solutions that show a negative deviation from Raoult's law form maximum boiling azeotropes. Water and Nitric acid $\to$ forms a maximum boiling azeotrope.