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Question

The more positive the value of E, the greater is the tendency of the species to getreduced. Using the standard electrode potential of redox couples given below find outwhich of the following is the strongest oxidising agent. E values:
Fe3+/Fe2+=+0.77;I2(s)/I=+0.54;
Cu2+/Cu=+0.34;Ag+/Ag=+0.80V

A
Fe3+
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B
I2(s)
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C
Cu2+
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D
Ag+
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Solution

The correct option is D Ag+
Given E0 values : Fe3+/Fe2+=+0.77V; I2(s)/I=+0.54V; Cu2+/Cu=+0.34V; Ag+/Ag=+0.80V
Since Strongest oxidising agent means it has greater tendency to oxidise other species and itself gets easily reduced. So higher the E0 values, stronger is the oxidising agent it is. Thus,Ag+ having highest positive E0 value among the given systems, is the strongest oxidising agent.

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