The most basic among the following is:

C H_{3} - N H_{2}

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C H_{3} - C H_{2} - N H_{2}

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C H_{3} - N H - C H_{3}

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C H_{3} - C H (C H_{3}) - N H_{2}

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Solution

The correct option is C $C H_{3} - N H - C H_{3}$
Methyl group has positive inductive effect. In option (c), nitrogen atom is connected with two methyl groups on both side. Hence, the inductive effect of two methyl groups increase the density of electrons on N-atom. Therefore, it will become more basic.

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