The nature of the precipitate formed when sodium hydroxide reacts with iron (II) sulphate is of
iron (II) hydroxide which is dirty green in colour and insoluble in excess of NaOH.
The reaction of sodium hydroxide with iron(II) sulphate is shown below:
FeSO4+2NaOH→Na2SO4+Fe(OH)2(↓)
The precipitated iron (II) hydroxide is dirty green in colour and is insoluble in excess of NaOH.