The number of sulphur atoms in 0.1 mol of S8 is
1 mole of S8 = 6.022 × 1023 molecules
0.1 mole of S8 = 6.022 × 1023 ×0.1 = 6.022 × 1022 molecules
1 molecule of S8 has 8 atoms of sulphur.
6.022 × 1023 ×0.1 molecules of S8 has 8 × 6.022 × 1023 × 0.1 atoms of S = 48.176 × 1022 atoms