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Question

The number of unpaired electrons in Co in the complex ion [Co(C2O4)3]3− is [Atomic number of Co=27]

A
4
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B
3
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C
Zero
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D
5
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Solution

The correct option is A 4

[CO(C2O4)3]3
Charge of oxalate ion is 2
Charge on CO is CO+(2)=3
CO=+3
Hybridisation of CO3+ is (Refer to Image 1)
C2O24 is weal field ligand so forms high spin complex
(Refer to Image 2)
Number of unpaired electrons=4.

1056610_1117491_ans_cea3e0007c0d4a6c9a12614a585c2de4.png

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