The only cations present in a slightly acidic solution are Fe3+,Zn2+ and Cu2+. The reagent that when added in excess of this solution would identify and separate Fe3+ in one step is:
6M NH3
Fe3+dul.NH3−−−−−→excessFe(OH)3ppt↓
Zn2+dul.NH3−−−−−→excess[Zn(NH3)4]2+
Cu2+dul.NH3−−−−−→excess[Cu(NH3)4]2+