The orange solid on heating gives a colorless gas and a green solid which can be reduced to metal by aluminum powder. The orange and the green solids are, respectively:
A
(NH4)2Cr2O7 and Cr2O3
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B
Na2Cr2O7 and Cr2O3
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C
K2Cr2O7 and CrO3
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D
(NH4)2CrO4 and CrO3
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Solution
The correct option is B(NH4)2Cr2O7 and Cr2O3 Orange solid is ammonium dichromate (NH4)2Cr2O7orangesolidΔ−→N2colourlessgas↑+Cr2O3greensolid+4H2O Cr2O3+2Al⟶2Cr+Al2O3