The order of acidic strength of HOCl,HClO2,HClO3 and HClO4 are:
A
HClO4>HClO3>HClO2>HClO
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B
HClO>HClO2>HClO3>HClO4
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C
HClO3>HClO4>HClO2>HClO
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D
HClO3>HClO2>HClO>HClO4
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Solution
The correct option is AHClO4>HClO3>HClO2>HClO Oxygen is more electronegative than chlorine. With an increase in the number of O atoms attached to Cl, more electrons are pulled away from O−H bond and more weaker becomes the O−H bond. This increases the acid strength. The decreasing order of acidic strength is HClO4>HClO3>HClO2>HClO.