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Question

The order of acidic strength of HOCl,HClO2,HClO3 and HClO4 are:

A
HClO4>HClO3>HClO2>HClO
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B
HClO>HClO2>HClO3>HClO4
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C
HClO3>HClO4>HClO2>HClO
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D
HClO3>HClO2>HClO>HClO4
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Solution

The correct option is A HClO4>HClO3>HClO2>HClO
Oxygen is more electronegative than chlorine. With an increase in the number of O atoms attached to Cl, more electrons are pulled away from OH bond and more weaker becomes the OH bond. This increases the acid strength.
The decreasing order of acidic strength is HClO4>HClO3>HClO2>HClO.

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