The order of heat of hydrogenation in following compound is:
A
I<II<IV<III
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B
III<IV<II<I
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C
II<III<I<IV
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D
II<IV<I<III
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Solution
The correct option is AIII<IV<II<I
The heat of hydrogenation is proportional to the number of α−hydrogen and stability of alkene. III is more stable as it contains more hyper conjugation and resonance stabilized. Then IV is stable due to resonance and less hyperconjugation than first. In I and II, α−hydrogen is more in II than first, therefore, II is more stable than first. Therefore the order is III<IV<II<I.