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Question

The oxidation state of S atom in [HSO4]− is


A

+2

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B

+4

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C

+6

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D

-2

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Solution

The correct option is C

+6


Since this is not a neutral compound the sum of oxidation numbers of all the elements will not be equal to 0 here. Instead, it will be equal to the charge on the ion.
We know that

O.N. of (O) = -2

O.N. of (H) =+1
Let the oxidation number for sulphur be x
So we can formulate the equation of oxidation numbers as given below.

[HSO4]1+x+4(2)=1
x=+6
Hence, the oxidation number of sulphur in
[HSO4] ion is +6


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