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Question

The oxide of an element contains 67.67% oxygen and the vapour density of its volatile chloride is 79. Equivalent weight of the element is :

A
2.46
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B
3.82
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C
4.36
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D
4.96
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Solution

The correct option is D 3.82
100 g of the oxide will contain 67.67 g of oxygen and 32.33 g of the element.
Equivalent weight of an element is its weight which reacts with 8 gm of oxygen to form oxide.
67.67 g of oxygen combines with 32.33 g of the element to form oxide.
1 g of oxygen will combine with 32.3367.67 g of element to form oxide.
8 g of oxygen will combine with 8×32.3367.67=3.82 g of element to form oxide.
Hence, the equivalent weight of the element is 3.82.

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