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Halides of Group 16

The product f...

Question

The product formed in the reaction of $S O C l_{2}$ with white phosphorous is:

A

P C l_{3}

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B

S O_{2} C l_{2}

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C

S C l_{2}

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D

P O C l_{3}

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Solution

The correct option is A $P C l_{3}$

White phosphorus on reaction with thionyl chloride (SOCl2) produces phosphorus trichloride

$P_{4 (s)} + 8 S O C l_{2 (l)} \to 4 P C l_{3 (l)} + 4 S O_{2 (g)} + 2 S_{2} C l_{2 (g)}$

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