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Question

The product formed in the reaction of SOCl2 with white phosphorous is:

A
PCl3
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B
SO2Cl2
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C
SCl2
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D
POCl3
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Solution

The correct option is A PCl3

White phosphorus on reaction with thionyl chloride (SOCl2) produces phosphorus trichloride

P4(s)+8SOCl2(l)4PCl3(l)+4SO2(g)+2S2Cl2(g)

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