Given: The atomic masses of H 1 2 is 2.014102 u, H 1 3 is 3.016049 u, C 6 12 is 12.000 u and N 10 20 e is 19.992439 u.
(i)
The given nuclear reaction is,
H 1 1 + H 1 3 → H 1 2 + H 1 2
The Q-value of the reaction is given as,
Q-value=( m i − m f ) c 2 =[ m( H 1 1 )+m( H 1 3 )−2m( H 1 2 ) ] c 2
Where, the sum of initial mass is m i and the sum of final mass is m f .
By substituting the given values in the above equation, we get
Q-value=[ 1.007825−3.016049−2×2.014102 ] c 2 =( −0.00433 c 2 ) u
We know that,
1 u=931.5 MeV/ c 2
Therefore, the required Q-value is,
Q-value=−0.00433×931.5 =−4.0334 MeV
Since, the Q-value is negative therefore, the reaction is endothermic in nature.
Thus, the reaction H 1 1 + H 1 3 → H 1 2 + H 1 2 is endothermic in nature.
(ii)
The given nuclear reaction is,
C 12 6 + C 12 6 → N 10 20 e+ H 2 4 e
The Q-value of the reaction is given by,
Q-value=( m i − m f ) c 2 =[ 2m( C 12 6 )−m( N 10 20 e )−m( H 2 4 e ) ] c 2
By substituting the given values in equation (4), we get
Q-value=[ 2×12−19.992439−4.002603 ] c 2 =( 0.004958 c 2 ) u =0.004958 c 2 ×931.5 MeV/c 2 =4.618377 MeV
Since, the Q-value is negative therefore the reaction is exothermic in nature.
Thus, the reaction C 12 6 + C 12 6 → N 10 20 e+ H 2 4 e is exothermic in nature.