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Question

The range of oxidation states exhibited by most elements in group V of the periodic table (N.P. As Sb. Bi) is

A
-3 to +1
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B
-3 to +3
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C
-3 to +5
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D
-2 to +3
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E
+1 to +5
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Solution

The correct option is D -3 to +5
Common oxidation state of group 5 elements are 3,+3 and +5.
Nitrogen shows +1,+2,+4 oxidation state. All oxidation state from +1 to +4 disproportionate in acid solution in case of nitrogen. Phosphorous shows +1 and +4 oxidation states in some oxoacids. All intermediate oxidation state disproportionate in acid and alkali into 3 and +5. However, +3 oxidation state for Ar,Sb,Bi become increasingly stable with respect to disproportionation.

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