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Question

The rate constant for the reaction, 2N2O54NO2+O2, is 3.0×105sec1. If the rate is 2.40×105mol litre1sec1, then the concentration of N2O5 ( in mol litre1) is:

A
1.4
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B
1.1
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C
0.04
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D
0.8
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Solution

The correct option is A 0.8
The given reaction is:

2N2O54NO2+O2

The unit of rate constant indicates its first-order reaction.

Rate=K[N2O5] (Rate Law)

where K= Rate constant

Given that,
K=3×105sec1
Rate=2.4×105molL1s1

Putting the given values in rate law:-

2.4×105=3.0×105[N2O5]

810=[N2O5]

[N2O5]=0.8 molL1

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