The rate law for the dimerisation of NO2 is −d[NO2]dt=k[NO2]2. Which of the following changes will change the value of the specific rate constant (k)?
A
Doubling the total pressure on the system
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B
Doubling the temperature
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C
Both A and B
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D
None of these
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Solution
The correct option is B Doubling the temperature The value of the specific reaction rate (or rate constant) depends on temperature but it is independent of the concentration of reactants or products or total pressure. Thus, doubling the temperature will change the value of the specific reaction rate.