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Question

The ratio of the frequencies of the long wavelength limits of the Balmer and Lyman series of hydrogen is

A
27:5
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B
5:27
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C
4:1
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D
1:4
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Solution

The correct option is D 27:5
Longest wavelengths are formed when the electron falls from next highest orbit to the orbit of the series releasing the minimum amount of energy.
E(Balmer)=K[114]=3k4 --------- (I)
E(Lyman)=K[1419]=5K36----------(II)
Ratio of (I) and (II),
Balmer : Lyman
=3K4×365K

=27:5

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