The ratio of the oxidation state of P in H3PO3 and H3PO4 is
Since both H3PO3 and H3PO4 are stable compounds, the sum of oxidation number of their respective elements adds up to zero.
Considering the oxidation number of P to be 'x',
For H3PO3, 3 × (+1) + x + (3 × (−2) = 0
⇒ x − 3 =0
⇒ x = 3
For H3PO4, 3 × (+1) + x + (4 × (−2) = 0
⇒ x − 5 =0
⇒ x = 5
Thus, the ratio of the oxidation state of P in H3PO3 and H3PO4 is 3:5.