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Question

The reaction of CH3MgBr on dry ice followed by acid hydrolysis gives:

A
acetic acid
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B
formic acid
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C
acetone
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D
acetaldehyde
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Solution

The correct option is A acetic acid
RMgX+CO2RCOOH.

Grignard reagents react with dry ice (solid CO2) followed by aqueous acid work-up to give carboxylic acids. Note that the carboxylic acid contains one extra C atom compared to the original halide from which the Grignard reagent was prepared.
Hence acetic acid shall be formed .(option (A))

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