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Question

The reaction of Q with PhSNa yields an organic compound (major product) that gives positive Carius test on treatment with Na2O2 followed by addition of BaCl2. The correct option(s) for Q is/are:

A
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B
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C
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D
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Solution

The correct option is D
In option (b) and (c), NO2 group (an EWG) is not present at ortho or para position w.r.t. the leaving group, so ArSN2 reaction will not be possible.



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