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Question

The reaction(s) which (do) not occur in the reduction zone in the extraction of iron from haematite ore is (are):-

A
Fe2O3+CO2FeO+CO2
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B
FeO+COFe+CO2
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C
Fe2O3+3C2Fe+3CO
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D
CaO+SiO2CaSiO3
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Solution

The correct options are
C Fe2O3+3C2Fe+3CO
D CaO+SiO2CaSiO3
Extraction
of iron is based on the reduction of Haematite (Fe2O3)
with carbon.
The
process of the extraction of iron is carried out by the following steps:

1)
Concentration of ore
2)
Calcination or Roasting of ore
3)
Reduction of ore
Reduction of ore:
The blast oxidizes carbon to CO2.
$C+O_2\rightarrow

CO_2
+heat
$.
Formation
of CO2 is an exothermic reaction in which a huge amount of heat
is liberated which rises the temperature to 1900OC
in this region. As the CO2 passes upwards, it reacts more coke
to form carbon monoxide
.$CO_2+C\rightarrow

2CO
$.
Reactions
in blast furnace;
Fe2O3+3C2Fe+3CO
Fe3O4+4CO3Fe+4CO2

CO2+C2CO
Overall
reaction
;
Fe2O3+3CO2Fe+3CO2..
Slag
formation:CaCO3CaO+CO2.
.
CaO+SiO2CaSiO3.
So the reactions in the options A,B are not preesent
Hence options C, D are correct.

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