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Question

The reagent which is used to distinguish between propene and propyne is

A
Bromine
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B
Alkaline KMnO4
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C
Ammoniacal AgNO3
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D
Ozone
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Solution

The correct option is C Ammoniacal AgNO3
Tollen's reagent (ammoniacal silver nitrate) reacts with terminal acetylenes to form the silver acetylide which precipitates out of solution

RC ≡ CH+AgNO3+NH4OH⟶RC ≡ CAg↓+NH4NO3+H2O

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