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Byju's Answer
Standard XII
Chemistry
Features of MOT
the relation ...
Question
the relation between energf activation and rate constant K1 K2 and temperature T1 T2
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Solution
Dear student,
The relation between activation energy, rate constant and temperature is given as follows:
ln
K
2
K
1
=
E
a
R
1
T
1
-
1
T
2
w
h
e
r
e
E
a
i
s
t
h
e
a
c
t
i
v
a
t
i
o
n
e
n
e
r
g
y
K
1
a
n
d
K
2
a
r
e
t
h
e
r
a
t
e
c
o
n
s
tan
t
s
T
1
a
n
d
T
2
a
r
e
t
e
m
p
e
r
a
t
u
r
e
s
Regards
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0
Similar questions
Q.
Activation energy
(
E
a
)
and rate constants (
k
1
and
k
2
) of a chemical reaction at two different temperature (
T
1
and
T
2
) are related by:
Q.
Activation energy
(
E
a
)
and rate constant
(
k
1
and
k
2
)
of a chemical reaction at two different temperatures
(
T
1
and
T
2
)
are related by:
Q.
If
k
1
=
rate constant at temperature
T
1
and
k
2
=
rate constant at temperature
T
2
for a first-order reaction, then which of the following relations is correct?
[
E
a
=
activation Energy]
Q.
A reaction can take place by two paths.
k
1
and
k
2
are rate constants for the two paths &
E
1
and
E
2
are their respective activation energies.
At temperature
T
a
:
k
1
>
k
2
,
E
1
<
E
2
Its temperature is raised to
T
b
, the rate constants change to
k
′
1
&
k
′
2
. Which relation is correct between
k
1
,
k
2
,
k
′
1
&
k
′
2
(considering activation energy does not change with temperature)?
Q.
The activation energy for forward and backward reactions are
50
k
J
/
m
o
l
and
40
k
J
/
m
o
l
respectively. If
K
1
and
K
2
are the equilibrium constants of reaction at temperature
T
1
and
T
2
respectively and
T
2
>
T
1
then:
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