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Question

The relation between internal energy U, pressure P and volume V of a gas in an adiabatic process is: U = a + bPV where a = b = 3. The ratio of specific heats is (Answer up to two decimal places)

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Solution

For an adiabatic process,
dQ = dU + PdV = 0 d[a+bPV] + PdV = 0bPdV + bVdP + PdV = 0(b+1)PdV + bVdP = 0(b+1)dVV + bdPP = 0(b+1)logV + blogP = constant;logVb+1 + logPb = constantPV(b+1)/b = constant γ = b+1b = 43 = 1.33

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