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Question

The resultant dipole moment μ of two compound of NOF and NO2F is 1.81 D and 0.47 D respectively.Which dipole moment do you predict?

A
1.81 D for NO2F and 0.47 D for NOF
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B
0.47 D for NO2F and 1.81 D for NOF
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C
For both NO2F and NOF, dipole moment (μ) is 1.81D
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D
For both NO2F and NOF. Dipole moment (μ) is 0.47 D
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Solution

The correct option is B 0.47 D for NO2F and 1.81 D for NOF
NOF has bent shape and NO2F has trigonal planar shape with asymmetrical distribution of charge on central atom. The dipole moment in case of NO2F is less than NOF due to its symmetrical shape. Hence, dipole moment of NO2F should be 0.47 D and that of NOF should be 1.81 D.

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