The soldiers of Napoleon army while at Alps during freezing winter suffered a serious problem as regards to the tin buttons of their uniforms. White metallic tin buttons got converted to grey powder. This transformation is related to:
A
a change in the crystalline structure of tin
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B
an interaction with nitrogen of the air at very low temperatures
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C
a change in the partial pressure of oxygen in the air
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D
an interaction with water vapour contained in the humid air
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Solution
The correct option is A a change in the crystalline structure of tin As temperature decreases, white tin (β−form) changes to grey tin (α−form).
β−Sn⟶α−Snat132oC
α−Sn has much less density than β−Sn. It undergoes a change in crystalline structure.