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Question

The soldiers of Napoleon army while at Alps during freezing winter suffered a serious problem as
regards to the tin buttons of their uniforms. White metallic tin buttons got converted to grey powder.
This transformation is related to:

A
a change in the crystalline structure of tin
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B
an interaction with nitrogen of the air at very low temperatures
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C
a change in the partial pressure of oxygen in the air
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D
an interaction with water vapour contained in the humid air
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Solution

The correct option is A a change in the crystalline structure of tin
As temperature decreases, white tin (βform) changes to grey tin (αform).
βSnαSnat132oC

αSn has much less density than βSn. It undergoes a change in crystalline structure.

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