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Question

The stability constans of the complexes formed by a metal ion M2+ with NH3,CN−H2O are of the order of 1015,1027,1011 respectively. Then :

A
NH3 is the strongest ligand
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B
CN is the strongest ligand
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C
These values cannot predict the strength of the ligand
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D
All the ligands are equally strong
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Solution

The correct option is B CN is the strongest ligand
The stability constants of the complexes formed by a metal ion M2+ with NH3,CNH2O are of the order of 1015,1027,1011 respectively. Then CN is the strongest ligand as the value of the stability constant for the complex between metal ion M2+ and CN ligand is maximum.

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