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Question

The stability order of the following carbocation is:
990336_bdc1ed204e90451dadc6f2b933e0b579.png

A
II>IV>III>I
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B
IV>II>III>I
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C
II>III>I>IV
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D
I>III>II>IV
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Solution

The correct option is C II>III>I>IV
IV has an anti-aromatic ring and hence is the least stable. II has the carbocation in conjugation with 2 double- bonds whereas III has it in conjugation with only 1 double bond.

Hence, II will be more stable than III. There is no such conjugation in I.

Therefore, the order of stability is II>III>I>IV

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