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Question

The standard heats of formation of CCl4 (g), H2O (g), CO2 (g) and HCl (g) at 298K are25.5,57.8,94.1 and22.1 kcal mol1 respectively. ΔH0 (298K) for the reaction CCl4 (g)+2H2O (g)CO2 (g)+4HCl (g)

A
+82.8 kcal mol1
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B
82.8 kcal mol1
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C
+41.4 kcal mol1
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D
41.4 kcal mol1
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Solution

The correct option is D 41.4 kcal mol1
We are given the standard heat of formation of reactant and products.
we know that,
ΔH0r=ΔfH0 (products)ΔfH0 (reactants)

putting all the values,
=94.1+4(22.1)(25.52×57.8) kcal mol1 =41.4 kcal mol1

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