The standard reaction gibbs energy for the electrochemical reaction.
Cr2O2−7+2Fe+14H+→2Cr3++2Fe3++2H2O is −793 kJ mol−1. The standard cell potential is:
+ 1.37V
+ 4.11V
+ 2.74V
+ 2.05V
ΔG∘=−nFE∘cell
Here n=6,
−793×103=−6×96500×E∘cell
E∘cell=+1.3696
≈1.37V
The standard reaction Gibbs energy for the electrochemical reaction,
Cr2O2−7+2Fe+14H+→2Cr3++2Fe3++2H2O, is −793 kJ mol−1. The standard cell potential is Volts.
The cell in which the following reactions occurs:
has = 0.236 V at 298 K.
Calculate the standard Gibbs energy and the equilibrium constant of the cell reaction.