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Question

The standard reduction potentials for Cu2+/Cu;Zn2+/Zn;Li+/Li;Ag+/Ag and H+/H2 are +0.34V,−0.762V,−3.05V,+0.80V and 0.00V respectively. Choose the strongest reducing agent among the following :

A
Zn
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B
H2
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C
Ag
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D
Li
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Solution

The correct option is D Li
Higher the negative value of reduction potential, stronger will be the reducing agent.

Hence, the correct order of reducing power is:

Li+/Li(3.05V)>Zn2+/Zn(0.762V)>H+/H2(0.00V)>Cu2+/Cu(+0.34V)>Ag+/Ag(+0.80V)

i.e., Li is the strongest reducing agent among the given elements.

Hence, the correct answer is option D.

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